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- Title
C-N, C-O and C-S Ullmann-Type Coupling Reactions of Arenediazonium o -Benzenedisulfonimides.
- Authors
Antenucci, Achille; Dughera, Stefano
- Abstract
Arenediazonium o-benzenedisulfonimides have been used as efficient electrophilic partners in Cu(I) catalysed Ullmann-type coupling. The synthetic protocols are mild and easy, and produced either N-alkylanilines, aryl ethers, or thioethers in fairly good yields (18 positive examples, average yield 66%). o-Benzenedisulfonimide was recovered at the end of the reactions and was reused to prepare the starting salts for further reactions. It is noteworthy that diazonium salts have been used as electrophilic partners in the Ullmann-type protocol for the first time.
- Subjects
DIAZONIUM compounds; COUPLING reactions (Chemistry); COPPER; ELECTROPHILES; ETHERS
- Publication
Reactions (2624-781X), 2022, Vol 3, Issue 2, p300
- ISSN
2624-781X
- Publication type
Article
- DOI
10.3390/reactions3020022