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- Title
An ionic Cd/Hg mixed-metal complex with an aminoalcohol ligand.
- Authors
Mardani, Zahra; Kazemshoar-Duzduzani, Reza; Moeini, Keyvan; Darroudi, Majid; Carpenter-Warren, Cameron; Slawin, Alexandra M.Z.; Woollins, J. Derek
- Abstract
A cadmium–mercury mixed-metal complex of cis-2-((2-((2-hydroxyethyl)amino)ethyl)amino)cyclohexan-1-ol (HEAC), [Cd(HEAC)2][HgI4] (1), was prepared and identified by elemental analysis, FT-IR, 1H NMR spectroscopy, and single-crystal X-ray diffraction. The X-ray analysis revealed an ionic structure for 1 in which the cadmium and mercury atoms have CdN4O2 and HgI4 environments, with distorted octahedral and tetrahedral geometries, respectively. The packing of the components in the crystal of 1 is supported by O–H···I hydrogen bonds, and these interactions lead to the formation of an R 4 4 ${\rm{R}}_4^4$ (22) motif.
- Subjects
CADMIUM compounds; METAL complexes; ALCOHOLS (Chemical class); LIGANDS (Chemistry); FOURIER transform infrared spectroscopy
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2018, Vol 73, Issue 12, p959
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2018-0158