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- Title
Iron-Containing Polyoxotungstophosphates and Products of Their Thermolysis.
- Authors
Moroz, Ya. A.; Lozinskii, M. S.; Zaritovskii, A. N.; Lopanov, A. N.; Burkhovetskii, V. V.; Glazunova, V. A.
- Abstract
Thermolysis of ferrocenium tungstophosphate [(C5H5)2Fe]3[PW12O40]∙H2O and tungstophosphatoferrates with the general formula Cat4[PW11O39Fe(H2O)]∙mH2O [Cat = (NH4)+, Rb+, Cs+, (CH3)4N+] and the Keggin anion structure were studied using differential scanning calorimetry, infrared spectroscopy, X-ray phase analysis, and electron microscopy. The crystalline products of their thermal decomposition, phases with the structure of pyrochlore and tungsten bronzes, were identified. The synthesized compounds are catalysts for the reactions of organic compounds oxidation and the production of carbon nanomaterials.
- Subjects
THERMOLYSIS; KEGGIN anions; CHEMICAL synthesis; DIFFERENTIAL scanning calorimetry; TUNGSTEN bronze
- Publication
Russian Journal of General Chemistry, 2023, Vol 93, Issue 7, p1774
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363223070198