We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Seed‐mediated Growth of Alloyed Ag‐Pd Shells toward Alkyne Semi‐hydrogenation Reactions under Mild Conditions<sup>†</sup>.
- Authors
Zheng, Yuqin; Tan, Taixing; Wang, Cheng
- Abstract
Main observation and conclusion: Ag@Ag‐Pdx core‐shell nanocomposites with various Ag/Pd ratio were deposited on Ag nanoplates using a seed growth method. When physically loaded on C3N4, Ag@Ag‐Pd0.077/C3N4 with optimized Ag/Pd ratio could accomplish high catalytic performance for the semi‐hydrogenation of phenylacetylene as well as other aliphatic (both terminal and internal alkynes) alkynes and phenylcycloalkynes containing functional groups (such as ester, hydroxyl, ethyl groups) under room temperature and 1 atm H2. The alloying and ensemble effects are used to interpret such catalytic performance.
- Subjects
ETHYNYL benzene; ETHYL group; ALKYNES; FUNCTIONAL groups; HETEROGENEOUS catalysis
- Publication
Chinese Journal of Chemistry, 2021, Vol 39, Issue 11, p3071
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.202100308