We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Sonochemical synthesis of a two‐dimensional supramolecular polymer with nanoporous morphology, linear thallophilic and covalent hydrogen‐bonding interactions.
- Authors
Yusefi, Sahar; Akhbari, Kamran; White, Jonathan; Phuruangrat, Anukorn
- Abstract
A new thallium‐based supramolecular polymer [Tl(μ3–3‐HClb)(μ3–3‐Clb)]n (1), (3‐HClb = 3‐chloroperbenzoic acid), has been synthesized and structurally characterized by single crystal X‐ray crystallography. It has a two‐dimensional structure with linear thallophilic and covalent hydrogen‐bonding interactions. In order to evaluate the effects of concentration, ultrasonic irradiation and type of solvents on structure, morphology and thermal behavior of 1, some experiments were designed, and eight samples of 1 were synthesized under different conditions. These samples were characterized by IR spectroscopy, thermogravimetric and differential thermal analyses, X‐ray powder diffraction and scanning electron microscopy. A new thallium based supramolecular polymer with two‐dimensional structure and linear thallophilic and covalent hydrogen bonding interactions was synthesized. By changing the reaction condition, various nanoporous morphologies of it can be prepared.
- Subjects
SONOCHEMISTRY; SUPRAMOLECULAR polymers synthesis; NANOPOROUS materials; SURFACE morphology; COVALENT bonds; HYDROGEN bonding
- Publication
Applied Organometallic Chemistry, 2019, Vol 33, Issue 3, pN.PAG
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.4747