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- Title
The reduction of 4‐nitrophenol and 2‐nitroaniline by palladium catalyst based on a KCC‐1/IL in aqueous solution.
- Authors
Baghbamidi, Sakineh Esfandiari; Hassankhani, Asadollah; Sanchooli, Esmael; Sadeghzadeh, Seyed Mohsen
- Abstract
KCC‐1/IL/Pd NPs can used as an excellent support for the synthesis of highly sparse homogeneous catalyst. KCC‐1 has high surface area that was functionalized with ionic liquid phase acting as the strong performers so that the Pd catalyst was well‐dispersed without aggregation on the framework of the KCC‐1/IL. This nano catalyst was specified by TGA, XRD, TEM, SEM, FT‐IR, and ICP. For reduction of 2‐nitroaniline and 4‐nitrophenol used from the KCC‐1/IL/Pd NPs as a green catalyst that showed excellent catalytic activities. Compared with the traditional substrate, KCC‐1 substantially increases protection and the accessibility of the nanoparticle sites due to its three dimensional hierarchical structure.
- Subjects
PALLADIUM catalysts; NITROPHENOLS; NITROANILINE; AQUEOUS solutions; CATALYST supports; CHEMICAL reduction
- Publication
Applied Organometallic Chemistry, 2018, Vol 32, Issue 4, p1
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.4251