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- Title
Heterotricyclodecane XI, Sulfoxide und Sulfone von 2-Oxa-7-thia-isotwistan und 2-Oxa-7-thia-twistan sowie Derivaten.
- Authors
Wigger, N.; Stücheli, N.; Szezepanski, H.; Ganter, C.
- Abstract
The synthesis of sulfoxides and sulfones of 2-oxa-7-thia-isotwistane ( 24) and 2-oxa-7-thia-twistane ( 35) as well as of several of their derivatives is described. endo-2-Hydroxy-9-thiabicyclo[3.3.1]non-6-ene ( 5) was used as starting material. During the course of the reactions special attention was given to intramolecular hydroxy-mercuration and jododemercuration reactions, spectroscopic features, molecular rearrangements and stereospecificity of oxidations of sulfides to sulfoxides.
- Publication
Helvetica Chimica Acta, 1972, Vol 55, Issue 8, p2791
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19720550809