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- Title
Synthesis, Structure, and X-Ray Photoelectron Spectra of Cobalt and Copper Complexes with 2-{(E)-[2-(4-Hydroxybutylamino)benzimidazol-1-yl]iminomethyl}phenol.
- Authors
Vlasenko, V. G.; Burlov, A. S.; Kuz'menko, T. A.; Kozakov, A. T.; Nikol'skii, A. V.; Trigub, A. L.; Levchenkov, S. I.
- Abstract
A new azomethine compound, 2-{(E)-[2-(4-hydroxybutylamino)benzimidazol-1-yl]iminomethyl}- phenol, and its cobalt(II) and copper(II) complexes were synthesized and characterized by IR, 1Н NMR, and X-ray photoelectron spectroscopy and quantum-chemical calculations. The crystal and molecular structures of the cobalt complex were established by X-ray diffraction analysis. The oxidation state of the cobalt ion in the complex after its crystallization from the solution was defined more exactly by X-ray photoelectron spectroscopy.
- Subjects
SCHIFF bases; PHOTOELECTRON spectra; MOLECULAR spectra; COBALT; METAL complexes
- Publication
Russian Journal of General Chemistry, 2018, Vol 88, Issue 12, p2550
- ISSN
1070-3632
- Publication type
Article
- DOI
10.1134/S1070363218120150