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- Title
Synthesis of β-Substituted meso-Tetraaryl-21,23-dithiaporphyrins by Heck Reaction.
- Authors
Forezi, Luana da S. M.; Gomes, Ana T. P. C.; Neves, Maria G. P. M. S.; Ferreira, Vitor F.; Boechat, Fernanda da C. S.; de Souza, Maria C. B. V.; Cavaleiro, José A. S.
- Abstract
meso-Tetraphenyl-21,23-dithiaporphyrin was selectively monobrominated at one β-pyrrolic position in good yields. This dithiaporphyrin was then functionalized by Heck reaction with styrene derivatives containing different electronic features. The reaction profile was found to depend on the electronic characteristics of the styrene derivatives; the new compounds were fully characterized.
- Subjects
PORPHYRIN synthesis; HECK reaction; SUBSTITUTION reactions; MACROCYCLIC compounds; STYRENE derivatives
- Publication
European Journal of Organic Chemistry, 2015, Vol 2015, Issue 27, p5909
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201500812