We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Synthesis of o‐carboranyl‐acyl‐substituted diazo compounds from B(4)‐acylmethyl carboranes and 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate.
- Authors
Maeng, Chanyoung; Ko, Gi Hoon; Lee, Kyungsup; Noh, Hee Chan; Park, Dae Su; Lee, Phil Ho
- Abstract
Reaction of B(4)‐acylmethyl o‐carborane with 2‐azido‐1,3‐dimethylimidazolinium hexafluorophosphate (ADMP) in the presence of 1,8‐diazabicyclo[5.4.0]‐undec‐7‐ene (DBU) in acetonitrile at 25 °C for 3 h produced a wide range of o‐carboranyl‐acyl‐substituted diazo compounds in high yields with good functional group tolerance.
- Subjects
CARBORANES; DIAZO compounds; FUNCTIONAL groups; ACETONITRILE; DIAZOTIZATION
- Publication
Bulletin of the Korean Chemical Society, 2023, Vol 44, Issue 8, p693
- ISSN
0253-2964
- Publication type
Article
- DOI
10.1002/bkcs.12708