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- Title
The Mixed Gold-Palladium Polyoxo-Noble-Metalate [NaAu<sup>III</sup><sub>4</sub>Pd<sup>II</sup><sub>8</sub>O<sub>8</sub>(AsO<sub>4</sub>)<sub>8</sub>]<sup>11−</sup>.
- Authors
Izarova, Natalya V.; Kondinski, Aleksandar; Vankova, Nina; Heine, Thomas; Jäger, Patrick; Schinle, Florian; Hampe, Oliver; Kortz, Ulrich
- Abstract
The first fully inorganic, discrete gold-palladium-oxo complex [NaAuIII4PdII8O8(AsO4)8]11− has been synthesized in aqueous medium. The combination of single-crystal XRD, elemental analysis, mass spectrometry, and DFT calculations allowed establishing the structure and composition of the novel polyanion, and UV/Vis studies suggest that it is stable in neutral aqueous media.
- Subjects
PALLADIUM compounds; AQUEOUS solutions; X-ray diffraction; MASS spectrometry; DENSITY functional theory; POLYANIONS; SINGLE crystals
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 28, p8556
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201403032