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- Title
Phenylene-Coated Magnetic Nanoparticles that Boost Aqueous Asymmetric Transfer Hydrogenation Reactions.
- Authors
Gao, Xiaoshuang; Liu, Rui; Zhang, Dacheng; Wu, Meng; Cheng, Tanyu; Liu, Guohua
- Abstract
Phenylene-coated organorhodium-functionalized magnetic nanoparticles are developed through co-condensation of chiral 4-(trimethoxysilyl)ethyl)phenylsulfonyl-1,2-diphenylethylene-diamine and 1,4-bis(triethyoxysilyl)benzene onto Fe3O4 followed complexation with [{Cp*RhCl2}2]. This magnetic catalyst exhibits excellent catalytic activity and high enantioselectivity in asymmetric transfer hydrogenation in aqueous medium. Such activity is attributed to the high hydrophobicity and the confined nature of the chiral organorhodium catalyst. The magnetic catalyst can be easily recovered by using a small external magnet and it can be reused for at least 10 times without loss of its catalytic activity. This characteristic makes it an attractive catalyst for environmentally friendly organic syntheses.
- Subjects
MAGNETIC nanoparticles; PHENYLENE compounds; ORGANORHODIUM compounds; CONDENSATION; HYDROGENATION; CATALYTIC activity
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 6, p1515
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201302797