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- Title
Studies on photochemical rearrangement of non‐oxygenated bicyclo[2.2.2]octenones and mono‐oxygenated bicyclo[2.2.2]octenones from masked o‐benzoquinones: Access to protoilludane and marasmane skeletons.
- Authors
Hung, Wei‐Chun; Chen, Yung‐Ching; Niu, Guang‐Hao; Chuang, Gary J.
- Abstract
In this work, we described flexible approaches to protoilludane‐like (5,6,4‐tricyclic ring) and marasmane‐like (5,6,3‐tricyclic ring) skeletons with naturally occurring cis/anti/cis stereochemistry using photochemical rearrangement of bicyclo[2.2.2]octenones and Diels‐Alder reaction of masked o‐benzoquinones as the key steps.
- Subjects
SKELETON; QUINONE; DIELS-Alder reaction; STEREOCHEMISTRY
- Publication
Journal of the Chinese Chemical Society, 2020, Vol 67, Issue 3, p383
- ISSN
0009-4536
- Publication type
Article
- DOI
10.1002/jccs.201900460