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- Title
ELECTROCHEMICAL DEPOSITION OF MAGNESIUM IN ETHEREAL GRIGNARD SALT SOLUTION WITH IONIC LIQUID ADDITIVE.
- Authors
NING LIU; LIDONG WANG; YAOMING WU; LIMIN WANG
- Abstract
The electrochemical deposition of magnesium was investigated in ethereal Grignard salt solution with tetraethylammonium bistrifluoro-methanesulfonimidate additive, using cyclic voltammetry, potentiostatic transients, and scanning electron microscope measurements. The voltammograms showed the presence of reduction and oxidation peaks associated with the deposition and dissolution of magnesium. From the analysis of the experimental current transients, it was shown that the magnesium deposition process was characterized as a three-dimensional nucleation. The deposited product obtained from potentiostatic reduction presented a generally uniform and dense film.
- Subjects
MAGNESIUM; GRIGNARD reagents; IONIC liquids; ELECTROCHEMICAL analysis; OXIDATION
- Publication
International Journal of Modern Physics B: Condensed Matter Physics; Statistical Physics; Applied Physics, 2009, Vol 23, Issue 6/7, p838
- ISSN
0217-9792
- Publication type
Article
- DOI
10.1142/S0217979209060117