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- Title
Thiourea-Catalyzed Cross-Dehydrogenative Coupling of C(sp<sup>3</sup>)-H with Diethyl Phosphite.
- Authors
Gu, Kai; Zhang, Zhiguo; Bao, Zongbi; Xing, Huabin; Yang, Qiwei; Ren, Qilong
- Abstract
The efficient thiourea-catalyzed cross-dehydrogenative coupling of C(sp3)-H with diethyl phosphite by using tert-butyl peroxide as a terminal oxidant was explored. This protocol further expands the application scope of H-bond donors and also provides facile access to biologically relevant α-amino phosphonic derivatives.
- Subjects
ORGANOCATALYSIS; COUPLING reactions (Chemistry); DEHYDROGENATION; CATALYTIC dehydrogenation; CHEMICAL bonds
- Publication
European Journal of Organic Chemistry, 2016, Vol 2016, Issue 23, p3939
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201600801