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- Title
Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex.
- Authors
Guo, Jing-Jing; Hu, Anhua; Chen, Yilin; Sun, Jianfeng; Tang, Haoming; Zuo, Zhiwei
- Abstract
A general strategy for the cleavage and amination of C−C bonds of cycloalkanols has been achieved through visible-light-induced photoredox catalysis utilizing a cerium(III) chloride complex. This operationally simple methodology has been successfully applied to a wide array of unstrained cyclic alcohols, and represents the first example of catalytic C−C bond cleavage and functionalization of unstrained secondary cycloalkanols.
- Subjects
AMINATION; CERIUM compounds; CARBON-carbon bonds; PHOTOCATALYTIC oxidation; COVALENT bonds
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 49, p15319
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201609035