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- Title
Inside Cover: Synthesis of a Stable Selenoaldehyde by Self-Catalyzed Thermal Dehydration of a Primary-Alkyl-Substituted Selenenic Acid (Angew. Chem. Int. Ed. 3/2015).
- Authors
Sase, Shohei; Kakimoto, Ryo; Goto, Kei
- Abstract
Depriving a selenenic acid (RCH2SeOH) of water results in its transformation into a selenoaldehyde (RCHSe). In their Communication on page 901 ff., K. Goto and co‐workers investigate the β‐dehydration reaction to form a CSe bond. The selenenic acid self‐catalyzes this transformation through a dehydrative condensation (to form a selenoseleninate intermediate) and a subsequent β‐elimination. A dendrimer‐type cradle protects both the selenenic acid and the selenoaldehyde, which are otherwise evanescent.
- Subjects
ANGEWANDTE Chemie (Periodical); SELENIC acid
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 3, p700
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201411162