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- Title
Azido and Tetrazolo 1,2,4,5-Tetrazine N-Oxides.
- Authors
Chavez, David E.; Parrish, Damon A.; Mitchell, Lauren; Imler, Greg H.
- Abstract
This study presents the synthesis and characterization of the oxidation products of 3,6-diazido-1,2,4,5-tetrazine ( 1) and 6-amino-[1,5- b]tetrazolo-1,2,4,5-tetrazine ( 2). 3,6-Diazido-1,2,4,5-tetrazine-1,4-dioxide was produced from oxidation with peroxytrifluoroacetic acid, and more effectively using hypofluorous acid, and 2 can be oxidized to two different products, 6-amino-[1,5-b]tetrazolo-1,2,4,5-tetrazine mono-N-oxide and di-N-oxide. These N-oxide compounds display promising performance properties as energetic materials.
- Subjects
AZIDO group; TETRAZINE; TRIFLUOROACETIC acid; HYPOFLUOROUS acid; NITROGEN oxide analysis
- Publication
Angewandte Chemie International Edition, 2017, Vol 56, Issue 13, p3575
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201612496