We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
The First Synthesis of the Sterically Encumbered Adamantoid Phosphazane P<sub>4</sub>(N<sup> t</sup>Bu)<sub>6</sub>: Enabled by Mechanochemistry.
- Authors
Shi, Yan X.; Xu, Kai; Clegg, Jack K.; Ganguly, Rakesh; Hirao, Hajime; Friščić, Tomislav; García, Felipe
- Abstract
All reported attempts to synthesize the tert-butyl-substituted adamantoid phosph(III)azane P4(N tBu)6 have failed, leading to the classification of this molecule as inaccessible and a literature example of steric control in chemistry of phosphorus-nitrogen compounds. We now demonstrate that this structure is readily accessible by a solvent-free mechanochemical milling approach, highlighting the importance of mechanochemical reaction environments in evaluating chemical reactivity.
- Subjects
PHOSPHAZANES; HETEROCYCLIC compounds synthesis; NITROGEN compound synthesis; MECHANICAL chemistry; CHEMICAL structure
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 41, p12736
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201605936