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- Title
Single‐Nitrogen Atom Incorporation into B=B Bond via the N=N Bond Splitting of Diazo Compound and Diazirine.
- Authors
Zhu, Lizhao; Kinjo, Rei
- Abstract
Triboraazabutenyne 3 is synthesized by the reaction of diboraazabutenyne 1 with aryl boron dibromide followed by the reduction. The ligand exchange to replace phosphine on the terminal sp2 B atom with carbene furnishes 4. 11B NMR, solid‐state structures, and computational studies disclose that 3 and 4 feature the extremely polarized B=B bond. 4 readily splits the N=N bond of both diazo compound and diazirine under ambient conditions, whereby one nitrogen atom is incorporated into the B=B moiety leading to a neutral diboraazaallene 6. The mechanism of the reaction between 4 and diazo compound is extensively investigated by density functional theory (DFT) calculations, as well as the isolation of an intermediate.
- Subjects
DIAZOMETHANE; DIAZO compounds; DENSITY functional theory; ATOMS
- Publication
Angewandte Chemie, 2023, Vol 135, Issue 33, p1
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.202306519