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- Title
NHC‐Rhodium‐Catalyzed Synthesis of Novel Silsesquioxanes Containing S‐Si and S‐Ge Bonds and Their Application in Hydrosilylation Process.
- Authors
Hanek, Kamil; Grzegorczyk, Kacper; Żak, Patrycja
- Abstract
The efficient and straightforward NHC‐rhodium‐catalyzed thiol‐silane and thiol‐germanane coupling reactions, leading to new classes of functionalized SQ‐based materials, are presented for the first time. The proposed strategies use commercially available reagents and show a broad functional groups tolerance, which opens a possibility of effective synthetic procedures of biologically active compounds.
- Subjects
SILICONES; COUPLING reactions (Chemistry); HYDROSILYLATION; BIOACTIVE compounds; SILANE; FUNCTIONAL groups
- Publication
ChemCatChem, 2024, Vol 16, Issue 9, p1
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.202301649