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- Title
Magnesium porphyrazine with peripheral methyl (3,5-dibromophenylmethyl)amino groups – synthesis and optical properties: Dedicated to the memory of Professor Franciszek Sączewski.
- Authors
Wieczorek, Ewelina; Piskorz, Jaroslaw; Popenda, Lukasz; Jurga, Stefan; Mielcarek, Jadwiga; Goslinski, Tomasz
- Abstract
Novel magnesium(II) porphyrazine with peripheral methyl(3,5-dibromophenylmethyl)amine groups was synthesized in a multi-step procedure starting from commercially available diaminomaleonitrile. All intermediates and the final macrocycle were characterized using UV–Vis, FT-IR, MS and various NMR techniques. The absorption and emission properties of the macrocycle were evaluated in N,N-dimethylformamide, dimethyl sulfoxide, and dichloromethane. The potential photosensitizing activity was evaluated by assessing the ability of the macrocycle to generate singlet oxygen in dimethyl sulfoxide and N,N-dimethylformamide.
- Subjects
MAGNESIUM compounds; PORPHYRAZINES; MACROCYCLIC compounds; DIMETHYLFORMAMIDE; DIMETHYL sulfoxide
- Publication
Heterocyclic Communications, 2019, Vol 25, Issue 1, p1
- ISSN
0793-0283
- Publication type
Article
- DOI
10.1515/hc-2019-0001