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- Title
Rhodium(III)-Catalyzed Alkenylation Reactions of 8-Methylquinolines with Alkynes by C(sp<sup>3</sup>)H Activation.
- Authors
Liu, Bingxian; Zhou, Tao; Li, Bin; Xu, Shansheng; Song, Haibin; Wang, Baiquan
- Abstract
The alkenylation reactions of 8-methylquinolines with alkynes, catalyzed by [{Cp*RhCl2}2], proceeds efficiently to give 8-allylquinolines in good yields by C(sp3)H bond activation. These reactions are highly regio- and stereoselective. A catalytically competent five-membered rhodacycle has been structurally characterized, thus revealing a key intermediate in the catalytic cycle.
- Subjects
RHODIUM; ALKENYLATION; ALKYNES; ORGANIC chemistry; RHENIUM
- Publication
Angewandte Chemie, 2014, Vol 126, Issue 16, p4275
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201310711