We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
As–N and As–N–P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls.
- Authors
Bresien, Jonas; Hinz, Alexander; Schulz, Axel; Villinger, Alexander
- Abstract
The isolation of binary As–N and ternary As–N–P cage compounds consisting exclusively of group 15 elements was achieved by exploiting the reactivity of diarsadiazanediyl. This arsenic centered biradical is capable of activating and/or quenching small molecules bearing double bonds such as diazenes, Ph–N=N–Ph, or in situ generated labile diphosphenes, e.g. Ph–P=P–Ph, leading to the formation of hexapnicta‐[2.1.1]bicyclohexanes.
- Subjects
CLATHRATE compounds; DIAZENES; DIPHOSPHENES; HEXANE; SMALL molecules; NITROGEN
- Publication
European Journal of Inorganic Chemistry, 2018, Vol 2018, Issue 15, p1679
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201800109