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- Title
Structural, Magnetic and Dielectric Properties of [(CH)NH]FeMn(HCOO).
- Authors
Zhao, Hongyang; Huang, Zhideng; Ma, Zhibin; Jia, Tingting; Kimura, Hideo; Fu, Qiuming; Wang, Geming; Tao, Hong; Cai, Kang; Fan, Ziran
- Abstract
The multiferroic phenomenon has interdisciplinary applications in the fields of chemistry, physics, electronics, materials, crystallography, and mechanics. Compared to traditional limited pure inorganic multiferroics, hybrid metal-organic frameworks are numerous and more flexible, and can be tailored to become different types of multiferroic materials. We synthesized [(CH)NH] FeMn(HCOO) and four crystals were obtained, with x = 0 (Mn), 0.1 (FeMn), 0.2 (FeMn), and 0.3 (FeMn). At the maximum Fe doping of FeMn, we observed magnetic properties different from lower-level-doped crystals. The magnetizations at 3 K were 3.50 emu/g, 3.87 emu/g, 3.89 emu/g and 7.38 emu/g corresponding to Mn, FeMn, FeMn and FeMn, respectively. FeMn has three magnetic transitions, at 118.3 K, 40.3 K, and 8.3 K.
- Subjects
MAGNETIC properties; DIELECTRIC properties; CRYSTALLOGRAPHY; MULTIFERROIC materials; CHEMISTRY; PHYSICS
- Publication
Journal of Electronic Materials, 2017, Vol 46, Issue 10, p5540
- ISSN
0361-5235
- Publication type
Article
- DOI
10.1007/s11664-017-5595-5