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- Title
Crystal structures of two dinuclear cadmium(II) complexes with Schiff bases as ligands.
- Authors
Hui, R.; Zhou, P.; You, Z.
- Abstract
Two new cadmium(II) complexes, Cd(L1)(NCS) ( 1) and Cd(L2)(NCS) ( 2), where L1 and L2 are the deprotonated forms of 2-[(3-dimethylaminopropylimino)methyl]-6-ethoxyphenol and 2-methoxy-6-[(pyridin-2-ylmethylimino)methyl]phenol, respectively, have been isolated as crystalline products and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction method. Both compounds are structurally similar and are phenolate-O-bridged dinuclear cadmium(II) complexes. Each Cd(II) cation in the complexes is octahedrally coordinated. The Cd Cd distances in ( 1) and ( 2) are 3.618(2) d 3.571(2)
- Subjects
CRYSTALS; MOLECULAR structure; CADMIUM; COMPLEX compounds; SCHIFF bases; LIGANDS (Chemistry); PHENOLS
- Publication
Journal of Structural Chemistry, 2010, Vol 51, Issue 6, p1201
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-010-0181-1