We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Simultaneous determination of selected hormones, endocrine disruptor compounds, and pesticides in water medium at trace levels by GC-MS after dispersive liquid-liquid microextraction.
- Authors
Chormey, Dotse; Büyükpınar, Çağdaş; Turak, Fatma; Komesli, Okan; Bakırdere, Sezgin
- Abstract
The need to enhance food safety has led to major advancements in pesticide productions, and though many benefits have been gained, environmental contamination has also risen from these chemicals that tend to persist in the environment. Some pesticides, together with other chemicals commonly called endocrine disruptor compounds, block the receptor sites of hormones or mimic displaced hormones, leading to imbalanced hormonal levels that result in health disorders and diseases. These chemicals occur at trace levels and are not directly detected by conventional analytical methods. A dispersive liquid-liquid microextraction method was therefore developed for preconcentration of 12 analytes including hormones, endocrine disruptor compounds, and pesticides, to be analyzed by gas chromatography mass spectrometry. This was achieved by optimizing parameters such as extractor solvent type and amount, dispersive solvent type and amount, pH, and salt effect that affect extraction output. The limits of detection and quantification of the developed method were between 0.09 and 3.36 and 0.31 and 11.19 ng mL, respectively. The calibration plots of the analytes also showed good linearity and low percent relative standard deviations. Recovery studies were performed for tap water and wastewater samples, and the percent recoveries recorded were between 84 and 109%.
- Subjects
ENDOCRINE disruptors -- Environmental aspects; PESTICIDE pollution; CHEMICAL preconcentration; GAS chromatography/Mass spectrometry (GC-MS); HORMONES
- Publication
Environmental Monitoring & Assessment, 2017, Vol 189, Issue 6, p1
- ISSN
0167-6369
- Publication type
Article
- DOI
10.1007/s10661-017-6003-6