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- Title
Synthesis and Crystal Structure of Rare Earth Selenates Nd(HSeO<sub>4</sub>)<sub>3</sub>,Sm(HSeO<sub>4</sub>)<sub>3</sub>, and Nd<sub>2</sub>(SeO<sub>4</sub>)<sub>3</sub> · 5H<sub>2</sub>O.
- Authors
Zakharov, M. A.; Troyanov, S. I.; Kemnitz, E.
- Abstract
Single crystals of rare earth (RE) selenates of the compositions Nd(HSeO4)3, Sm(HSeO4)3, and Nd2(SeO4)3· 5H2O are synthesized and studied by X-ray diffraction analysis at T = 297 and 180 K. It is established that Nd and Sm hydrogen selenates are isostructural to one another and to the corresponding hydrogen sulfates. Neodymium selenate pentahydrate is not isostructural to the analogous RE sulfates, although their structural motifs are similar.
- Subjects
CRYSTALS; X-ray diffraction; OPTICAL diffraction; HYDROGEN; NEODYMIUM; METALS; INORGANIC chemistry
- Publication
Crystallography Reports, 2004, Vol 49, Issue 5, p747
- ISSN
1063-7745
- Publication type
Article
- DOI
10.1134/1.1803300