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- Title
Copper(II) Nitrate Catalyzed Azide-Alkyne Cycloaddition Reaction: Study the Effect of Counter Ion, Role of Ligands and Catalyst Structure.
- Authors
Bihani, Manisha; Pasupuleti, Bala G.; Bora, Pranjal P.; Bez, Ghanashyam; Lal, Ram A.
- Abstract
Abstract: For the first time, CuAAC reaction catalyzed by copper(II) nitrate and counter ion effect of various copper(II) salts are reported. Use of a novel copper complex <bold>1</bold>, derived from the reaction of copper(II) nitrate with 5-acetyl-2-amino-6-methyl-4-(pyridin-3-yl)-4<italic>H</italic>-pyran-3-carbonitrile, facilitated the CuAAC reaction at room temperature with a catalyst loading as low as 1 mol% within a very short reaction time.Graphical Abstract: <graphic></graphic>
- Subjects
COPPER catalysts; METHYL acetate; METHYL acrylate; PYRAN synthesis; PYRIDINE
- Publication
Catalysis Letters, 2018, Vol 148, Issue 5, p1315
- ISSN
1011-372X
- Publication type
Article
- DOI
10.1007/s10562-018-2357-9