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- Title
Synthesis and Characterization of Dearomatized Pyridine‐Derived Alkyl‐Amido‐tert‐Butylphosphine Iron(II) Complexes.
- Authors
Gunasekera, Parami S.; Paul, Sanchita; MacMillan, Samantha N.; Lacy, David C.
- Abstract
Neutral three‐coordinate iron alkylidenes of the form PN−Fe=CHR have been proposed as viable candidates for alkene metathesis. Indeed, during the final stages of preparing this current study, a separate report disclosed that dearomatized PN−Fe‐alkyl complexes are active precatalysts for ring‐opening metathesis polymerization (ROMP) of norbornene implicating PN−Fe=CHR species as possible intermediates. In yet another separate report, we prepared Zn analogues of PN−Fe‐alkyl complexes and herein provide an account for the synthesis, characterization, and reactivity of some new iron complexes with the same tBu substituted PN platform.
- Subjects
IRON; RING-opening polymerization; METATHESIS reactions; ALKYLIDENES; ALKENES; COORDINATE covalent bond
- Publication
European Journal of Inorganic Chemistry, 2024, Vol 27, Issue 11, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202300757