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- Title
Synthesis and Characterization of Phosphate‐Catecholate Chelated Nd(III), Zr(IV), and Al(III) Complexes.
- Authors
Chen, Ting; Ju, Shaoying; Tong, Mengnan; Zhao, Yufen; Wu, Yile; Stephan, Douglas W.
- Abstract
Metal phosphates are important catalysts and materials in synthesis chemistry. Herein, we describe the synthesis and characterization of phosphate‐catecholate chelated Nd(III), Zr(IV) and Al(III) chlorides (2–5). These species are achieved via ethyl chloride elimination reaction of oxophosphoranes with corresponding metal chlorides. The product 2–5 represent a new serial of monometallic and bimetallic phosphate‐catecholate chelated metal complexes stabilized by both P−O and catecholate‐O donors. These findings pave the way for future explorations of such species in catalysis.
- Subjects
CHELATES; METAL chlorides; ELIMINATION reactions; CATALYST synthesis; METAL complexes
- Publication
European Journal of Inorganic Chemistry, 2023, Vol 26, Issue 30, p1
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.202300443