We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Oxochloroselenate(IV) with Incorporated {Cl<sub>2</sub>}: The Case of Strong Cl⋅⋅⋅Cl Halogen Bonding.
- Authors
Usoltsev, Andrey N.; Korobeynikov, Nikita A.; Kolesov, Boris A.; Novikov, Alexander S.; Abramov, Pavel A.; Sokolov, Maxim N.; Adonin, Sergey A.
- Abstract
Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol−1, according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
- Subjects
HALOGENS; RAMAN spectroscopy; SELENIUM compounds synthesis; CHEMICAL bonds; HALOGEN compounds; INCLUSION compounds
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 36, p9292
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202101024