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- Title
Gold-Catalyzed Diastereoselective Cycloisomerization of Alkylidene-Cyclopropane-Bearing 1,6-Diynes.
- Authors
Zheng, Hongchao; Adduci, Laura L.; Felix, Ryan J.; Gagné, Michel R.
- Abstract
An unprecedented gold-catalyzed diastereoselective cycloisomerization of 1,6-diynes bearing an alkylidene cyclopropane moiety has been developed. This methodology enables rapid access to a variety of 1,2-trimethylenenorbornanes, which are important building blocks in the preparations of abiotic and sesquiterpene core structures.
- Subjects
DIASTEREOISOMERIZATION; DIASTEREOISOMERS synthesis; GOLD; CYCLOISOMERIZATION; ALKYLIDENES; CYCLOPROPANE synthesis; FIRE assay
- Publication
Angewandte Chemie, 2014, Vol 126, Issue 30, p8038
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201405147