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- Title
Dysprosium Single‐Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change.
- Authors
Long, Jérôme; Basalov, Ivan V.; Forosenko, Natalia V.; Lyssenko, Konstantin A.; Mamontova, Ekaterina; Cherkasov, Anton V.; Damjanović, Marko; Chibotaru, Liviu F.; Guari, Yannick; Larionova, Joulia; Trifonov, Alexander A.
- Abstract
The synthesis, and magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands is reported. Magnetic investigations reveal a genuine single‐molecule magnet (SMM) behavior, with out‐of‐phase signals up to 60 K, and tunable emission arising from the Schiff base ligands. Slowly but surely: Schiff base dysprosium complexes exhibit single‐molecule magnet behavior with out‐of‐phase signals up to 60 K and tunable emission.
- Subjects
DYSPROSIUM; SINGLE molecule magnets; SCHIFF bases; LIGAND analysis; SUBSTITUENTS (Chemistry); PHOTOLUMINESCENCE
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 2, p474
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201804429