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- Title
Synthesis, characterization and crystal structure of a porous crystalline material.
- Authors
GuoChun Zhang
- Abstract
An exploration of the nickelmalatebpp system under hydrothermal conditions, has led to the isolation of a novel framework {[NiHmalbpp]·5H2O}n1 Hmal malate dianion, bpp 1,3bi4pyridylpropane. Singlecrystal Xray analyses reveal that it crystallizes in the orthorhombic space group Pccn. a 21.1413 Å, b 10.402816 Å, c 19.2503 Å. The NiII ions are linked into an extended helical chain via Hmal molecules. Further these chains are united together through the bridging bpp to form a 3D porous framework, which exhibits an unusual NbOtype topological network. © 2008 WILEYVCH Verlag GmbH & Co. KGaA, Weinheim
- Subjects
POROUS materials; CRYSTALLIZATION; NICKEL compounds; X-ray crystallography; SPACE groups; MATHEMATICAL crystallography
- Publication
Crystal Research & Technology, 2008, Vol 43, Issue 12, p1335
- ISSN
0232-1300
- Publication type
Article