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- Title
Microcalorimetry insight into size effect on standard molar reaction enthalpy of CdMoO<sub>4</sub> nanosystem.
- Authors
Yanfen Li; Rongli Jiang; Zaiyin Huang; Hui Lv; Lu Zhou; Tingyu Liu; Xiaoyu Zhang
- Abstract
Uniform CdMoO4 nanooctahedra with tunable sizes have been synthesised via a facile and mild microemulsion method at room temperature. The reaction between CdMoO4 nanooctahedra and dilute hydrochloric acid was in situ monitored using microcalorimetry at 298.15 K, and microcalorimetric heat flow curves from this reaction process were obtained. Combined with an inductively coupled plasma optical emission spectrometer technique, the size effect of CdMoO4 nanooctahedra on standard molar reaction enthalpy (ΔrHmƟ) was studied. The results indicate that the value of ΔrHmƟ decreased with decreased particle size.
- Subjects
MICROCALORIMETRY; CADMIUM compounds; ENTHALPY; NANOSTRUCTURED materials synthesis; HYDROCHLORIC acid; HEAT transfer; INDUCTIVELY coupled plasma atomic emission spectrometry
- Publication
Micro & Nano Letters (Wiley-Blackwell), 2013, Vol 8, Issue 8, p418
- ISSN
1750-0443
- Publication type
Article
- DOI
10.1049/mnl.2012.0974